Metals
And Non-Metals
Physical
properties of Metals and Non-Metals
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METALS
|
NON-METALS
|
|
Metals
are in solid state at room temperature.
(mercury
is in liquid state)
|
Non-metals
are usually gases or solid at room temperature
(bromine
is in liquid state)
|
|
Metals
are generally hard
(Sodium
and Potassium are soft)
Melting
and Boiling point is high
(Gallium
and Caesium melts on palm)
|
Non-metals
are generally soft.
Melting
and Boiling point is low
(Diamond
is hardest substance)
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|
Metals
are Lustrous
|
Non-metals
are non lustrous
(Iodine
is exception)
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|
Metals
are malleable
(Can
be beaten into sheets)
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Non-metals
are not malleable
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|
Metals
are ductile
(Can
be drawn into wires)
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Non-metals
are not ductile
|
|
Metals
are good conductors of electricity
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Non-metals
are bad conductors of electricity
(graphite
is good conductor)
|
|
Metals
are sonorous
(makes
sound when strike to hard surface)
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Non-metals
not sonorous
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Oxides
of metals are basic in nature
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Oxides
of non-metals are basic in nature
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¨ Chemical Properties
·
With Oxygen (metals burn in air)
Metal
+ Oxygen à Metal
Oxide
Copper
when heated in air, it combines with oxygen to form copper oxide (black oxide)
2Cu
+ O2 à2CuO
Aluminium
forms Aluminium oxide
4Al
+ 3O2 à 2Al2O3
In
general, Metal oxide is basic in nature.
Amphoteric Oxides – Some
of the metal oxides are Acidic as well as basic in nature.
They
react with both, acids as well as bases to produce salt and water.
Al2O3
+ 6HCl à 2AlCl3
+ H2O
Al2O3
+ 2NaOH à2NaAlO2
+ H2O
Metal
oxides are usually insoluble in water
Water
soluble metal oxides are called as “Alkalis”
Na2O
+ H2O à 2NaOH
K2O
+ H2O à 2KOH
Rate of reaction
of metals with Oxygen
§ Potassium
and Sodium react vigorously and catch fire if kept open.
(To
prevent accidental fires these metals are stored under kerosene)
§ A thin
oxide layer is formed on the surface of the metals like aluminium, magnesium,
zinc, etc. when exposed to air at ordinary temperature.
(This
oxide layer prevents the further oxidation of the metal)
§ Iron
does not burn on heating but iron filings burns vigorously when sprinkled in
the flame of the burner.
§ Copper
does not burn. But it forms a black layer of copper oxide when heated.
§ Silver
and Gold do not react with oxygen even at high temperature.
Anodising – This
is the process of forming a thick layer of Aluminium.
When
exposed to air, aluminium forms a thin oxide layer. This prevents the further
corrosion of the metal.
·
With water
Metal
+ Water à Metal
Oxide + Oxygen
Metal
Oxide + Water à Metal
Hydroxide
Sodium
and potassium reacts violently with cold water
The
reaction is highly exothermic and so the hydrogen released in the reaction
catches fire.
2K
+ 2H2O à 2KOH +
H2 + heat energy
2Na
+ 2H2O à 2NaOH
+ H2 + heat energy
The
reaction with Calcium too is exothermic. But the heat released is not
sufficient for hydrogen to catch fire.
Ca
+ 2H2O à Ca(OH)2
+ H2
ü Calcium
floats on water because the bubbles of hydrogen gas stick to the calcium metal.
ü Magnesium
reacts with hot water to form magnesium hydroxide and hydrogen.
Magnesium
too floats on water as the bubbles of hydrogen gas.
Aluminium,
Iron and Zinc reacts with steam to form its oxide and hydrogen.
2Al
+ H2O à Al2O3
+ 3H2
3Fe
+ 4H2O à Fe3O4
+ 4H2
Lead,
Copper, silver and gold do not react with water at all.
·
With Acids
Metal
+ Dilute Acid à Salt +
Hydrogen
Mg
+ 2HCl à MgCl2
+ H2
2Al
+ 6HCl à 2AlCl3
+ 3H2
Zn
+ 2HCl à ZnCl2
+ H2
2Fe
+ 6HCl à 2FeCl3
+ 3H2
The
reaction is different in case of Nitric Acid (HNO3)
ü Nitric
acid is a strong oxidising agent. It oxidise the oxygen produced to water and
itself gets reduced to nitrogen oxide.
Magnesium
and Manganese react with very dilute nitric acid to evolve H2
Reactivity
– Mg > Al > Zn > Fe
·
Metal with Solutions of other Metal Salts
Metal
A + Salt solution of B à Salt solution of B + Metal B
Reactive
metals displace less reactive metals from their compounds or molten state.
Fe
+ CuSO4 à FeSO4
+ Cu
Zn
+ CuSO4 à ZnSO4
+ Cu
·
Metals react with Non-Metals
Reactivity
à
tendency to attain stable electronic configuration
Noble
gases à stable
configuration
Formation of
sodium chloride
Sodium
(Na) – Atomic number – 11
Electronic
configuration – 2,8,1
Chlorine
(Cl) – Atomic number – 17
Electronic
configuration – 2,8,7
Sodium
loses one electron and forms Na+
Chlorine
gains one electron and forms Cl-
Sodium
and chlorine ions attract each other and are held by strong electrostatic force
of attraction and forms sodium chloride (NaCl)
Ionic Compounds – The
compounds formed by transfer of electrons from metal to non-metal are known as
ionic compounds
Formation of
Magnesium Chloride
Properties of
Ionic Compounds
1)
Physical nature – Ionic compounds are solids at room temperature. These
are hard substance due to the strong force of attraction.
2)
Melting and Boiling Point – MP and BP of ionic substances are too high
as large amount of energy is required to break the strong inter-ionic
attraction.
3)
Solubility – Ionic compounds are soluble in water and insoluble in
organic solvents like petrol, kerosene, etc.
4)
Conduction of electricity – Ionic compounds conducts electricity in its
solution or molten state. (Movement of ions is responsible for the
conductivity). They do not conduct electricity in its solid state.
Occurrence of
Metals
Earth’s
crust – major source of metals
Sea
water – soluble salts like sodium chloride, magnesium chloride
§ Minerals – The elements or
compounds which, occurs naturally in earth’s crust are known as minerals.
§ Ores – Minerals which
contain a very high percentage of particular metal is called Ores.
1)
Less Reactive Metals – Found in Free State (gold, silver, platinum and copper)
2)
Highly Reactive Metals – Never exists in Free State (K, Na, Ca, Mg, Al)
3)
Moderately reactive – these are found in earth’s crust in their oxides,
sulphides or carbonates form (Zn,Fe, Pb)
Steps involved in
extraction of metals
Metallurgy – The
process of extraction of metals from their respective ores is termed as
Metallurgy.
Gangue –
Impurities such as soil, sand, etc associated with the ores is called as
gangue.
Extraction of
metals
¨ Metals low in activity series
Oxides
of these metals are heated to reduce to metals.
2HgS
+ 3O2 à 2HgO +
2SO2
2HgO
à 2Hg +
O2
2CuS
+ 3O2 à 2Cu2O
+ 2SO2
2Cu2O
+ Cu2S à 6Cu
+SO2
¨ Metals in middle activity series
These
metals occur in the form of sulphide or carbonate ores.
Sulphides
and carbonates are converted to metal oxides.
Metals
oxides are then reduced to metal
Roasting –
Roasting is the process of strong heating sulphides ores in the presence of
excess air.
2ZnS
+ O2 à 2ZnO +
SO2
Calcination –
Calcination is the process of strong heating of carbonate ores in limited
supply of air.
ZnCO3
à ZnO +
CO2
Metal
oxides formed are reduced to metals b using suitable reducing agent (like
carbon)
ZnO
+ C à Zn +
CO
In
some cases, displacement reactions are used to reduce the metal oxide.
Highly
reactive metals displace and reduce the lesser reactive metal from it’s
compound.
3MnO
+ 4Al à 3Mn +
2Al2O3 + heat
Fe2O3
+ 2Al à 2Fe
+ Al2O3 + heat
¨ Metals on the top of Activity Series
Electrolytic
reduction method is used to obtain these metals.
Sodium,
Magnesium, Calcium, etc are obtained by electrolysis of their molten chlorides.
At
cathode Na+ + e- à Na
At
anode 2Cl- à Cl2
+ 2e-
Refining of metals
This
is the final step to get the purest form of metal by removing all the
impurities.
Electrolytic
refining is the method widely used for this.
Corrosion
Corrosion is the deterioration of a metal as a
result of chemical reactions between it and the surrounding environment.
Both the type of metal and the environmental
conditions, particularly gases that are in contact with the metal,
determine the form and rate of deterioration.
§ Silver
articles become black. This is because silver reacts with the sulphur in the air
and forms coating of silver sulphide.
§ Green
coat is formed on copper articles. Copper reacts with moist carbon dioxide and forms
a greenish coat of copper carbonate.
§ Iron
articles rusts. Iron when exposed to moist air forms a brown flaky substance
called rust.
Prevention of
corrosion
Rusting
is prevented by painting, oiling, greasing, galvanising, chrome plating,
anodising or making alloys.
Galvanisation
– Articles are coated with thin layer of Zinc.
Alloy – This
is the homogeneous mixture of two or more metals or a metal and a non-metal.
Steel
= Iron + Nickel + Chromium + carbon (very less)
Brass
= Copper + Zinc
Bronze
= Copper + Tin
Solder
= Lead + Tin (low MP. Used for welding)
Amalgam – An
Alloy in which one metal is mercury
Note
– Pure gold is very soft and not suitable for making jewellery.
Addition
of 2 parts of copper (or silver) to 22 parts of gold makes it hard.